نشریه علوم زمین خوارزمی

نشریه علوم زمین خوارزمی

ژئوشیمی زیست‌محیطی عناصر بالقوه سمّی در خاک‌های شهری و کشاورزی شهرستان اسلامشهر، جنوب تهران

نویسندگان
1 سازمان زمین شناسی و اکتشافات معدنی کشور
2 دانشگاه شاهرود
چکیده
به منظور بررسی ژئوشیمی زیست­محیطی عناصر بالقوه سمّی در خاک‌های شهری و کشاورزی اسلامشهر، جنوب تهران، 21 نمونه خاک سطحی برداشت شد و غلظت کل عناصر بالقوه سمّی با استفاده از دستگاه ICP-OES اندازه‌گیری شد. داده‌های به دست آمده با استفاده از محاسبه ضرایب ژئوشیمیایی و روش‌های آماری تجزیه و تحلیل شدند. بر اساس مقادیر میانگین ضریب غنی شدگی، ضریب زمین انباشت، شاخص تک عاملی، شاخص آلودگی یکپارچه نمرو و شاخص خطر اکولوژیکی بالقوه، برخی از ایستگاه‌ها نسبت به عناصر بالقوه سمّی به ویژه کادمیم، سرب، روی و منگنز آلوده هستند. با توجه به تحلیل‌های آماری، منشأ احتمالی عناصر کروم، مولیبدن، نیکل، آهن، روی، مس، کادمیم و سرب انسانزاد (شامل فعالیت‌های صنعتی، ترافیک، و دورریزی زباله‌­های شهری و صنعتی) می‌­باشد. ارزیابی خطر سلامتی نشان دهنده خطر غیرسرطانزایی سرب از طریق مسیر بلع برای کودکان در برخی ایستگاه‌­ها است. خطر احتمالی سرطان‌زایی کروم و نیکل برای کودکان از طریق مسیر بلع بزرگ‌تر از محدوده قابل قبول (4-10×1) می‌­باشد. نتایج این پژوهش، لزوم مدیریت زیست محیطی فعالیت‌های انسانی (ترافیک، کشاورزی و صنایع) به منظور کاهش پیامدهای منفی عناصر بالقوه سمّی برای ساکنان منطقه را مورد تأیید قرار می­‌دهد.
کلیدواژه‌ها

عنوان مقاله English

Environmental geochemistry of potentially toxic elements in urban and agricultural soils of Islamshahr County, south of Tehran

نویسندگان English

Mohamad hosein Arabamiri 1
Giti Forghani Tehrani 2
چکیده English

To investigate the enviromental geochemistry of potentially toxic elements (PTEs) in urban and agricultural soils of Islamshahr, south of Tehran, 21 top soil samples were collected and the total concentrations of PTEs were measured by an ICP-OES device. The obtained data were analyzed through the calculation of geochemical indices and the application of statistical methods. Based on the average values of the enrichment factor, geoaccumulation index, single factor index, Nemerow integrated pollution index (NIPI) and potential ecological risk index (PERI), the studied soil samples are polluted with Cd, Pb, Zn and Mn. The statistical analyses indicate that Cr, Ni, Fe, Zn, Cu, Cd and Pb originate from anthropogenic activities (e.g., industrial activities, traffic, urban and industrial waste disposal sites). Human health risk assessment shows the non-carcinogenic risk of Pb through ingestion for children in some sampling stations. The carcinogenic risk of Cr and Ni in the soils of the study area is higher than the acceptable value (1×10-4) for children through the ingestion route. The results of this study highlight the necessity of environmental management of human activities (traffic, agriculture, and industries) to reduce the negative consequences of potentially toxic elements intake by residents of the study area.

کلیدواژه‌ها English

potentially toxic elements
urban soil
Agriculture
Pollution
Islamshahr
Abrahim, G.M.S., Parker R.J., 2008. Assessment of heavy metal enrichment factors and the degree of contamination in marine sediments from Tamaki Estuary, Auckland, New Zealand. Environmental monitoring and assessment 136(1-3), 227-238.
Adimalla, N., Chen, J., Qian, H., 2020. Spatial characteristics of heavy metal contamination and potential human health risk assessment of urban soils: A case study from an urban region of South India. Ecotoxicology and Environmental Safety 194, 110406.
Alvarez, C.C., Comez, M.E.B., Zavala, A.H., 2021. Hexavalent chromium: Regulation and health effects. Journal of Trace elements in Medicine and Biology 65, 126729.
Arifin, Y.I., Rauf, J., Akase, N., Djibran, F.R., Nurfaika, E., Lakilo, A., Jahja, M., Sakakibara, M., 2025. Integrated geological mapping and spatial distribution of heavy metal contamination with geoaccumulation index assessment in Juriya’s artisanal gold mining region, Gorontalo, Indonesia. Journal of Hazardous Materials Advances 19, 100861.
CCME (Canadian Council of Ministers of the Environment), 2007. Canadian Soil Quality Guidelines for the Protection of Environmental and Human Health. Summary Tables, CCME Ottawa, Canada.
Chopin, E.I.B., Alloway, B.J., 2007. Distribution and mobility of trace elements in soils and vegetation around the mining and smelting areas of Tharsis, Ríotinto and Huelva, Iberian Pyrite Belt, SW Spain. Water, Air, and Soil Pollution 182 (1), 245-261.
Demetriades, A., Birke, M., 2015. Urban geochemical mapping manual: Sampling, Sample preparation, Analysis, Quality control check, Statistical processing and Map plotting. EuroGeoSurveys, Brussels.
Dulfour, A.P., Ballentine, A.R.K., 1986. Ambient Water Quality Criteria for Bacteria- 1986.
EFSA Panel on Contaminants in the Food Chain (CONTAM), 2010. Scientific Opinion on Lead in Food. EFSA Journal 8(4) 1570.
El Yaouti, F., El Mandour, A., Khattach, D., Benavente, J., Kaufmann, O., 2009. Salinization processes in the unconfined aquifer of Bou-Areg (NE Morocco): a geostatistical, geochemical, and tomographic study. Applied Geochemistry 24 (1), 16-31.
Escutia-Martinez, J., Hernandez-Cruz, E.Y., Avendano-Briseno, K.A., Pedraza-Chaverri, J., 2025. Vanadium toxicity and mitochondrial dysfunction: Health effects assessment, Caenorhabditis elegans as an emerging model, and the role of plant metabolites. Clinical Bionenergetics 1 (7), 1-25.
Fakhri,Y., Bjørklund, G., Bandpei, A.M., Chirumbolo, S., Keramati, H., Hosseini Pouya, R., Asadi, A., Amanidaz, N., Sarafraz, M., Sheikhmohammad, A., Alipour, M., Baninameh, Z., Mohseni, S.M., Sarkhosh, M., Ghasemi, S.M., 2018. Concentrations of arsenic and lead in rice (Oryza sativa L.) in Iran: a systematic review and carcinogenic risk assessment. Food and Chemical Toxicology 113, 267–277.
FAO/WHO, 1993. Evaluation of certain food additives and contaminants. 41st Meeting of the Joint FAO/WHO Expert Committee on Food Additives. World Health Organisation Technical Report Series no. 837, Geneva, Switserland.
Guo, G., Wu, F., Xie, F., Zhang, R., 2012. Spatial distribution and pollution assessment of heavy metals in urban soils from southwest China. Journal of Environmental Sciences 24(3), 410-418.
Hakanson, L., 1980. An ecological risk index for aquatic pollution control. A sedimentological approach. Water Research 14 (8), 975-1001.
Integrated Risk Information System (IRIS), 2020. Environmental protection agency, advanced research. U.S. https://cfpub.epa.gov/ncea/iris/search/index.cfm?keyword.
Jiang, C., Zhao, Q., Zheng, L., Chen, X., Li, C., Ren, M., 2021. Distribution, source and health risk assessment based on the Monte Carlo method of heavy metals in shallow groundwater in an area affected by mining activities, China. Ecotoxicology and Environmental Safety 224, 112679.
Johnson, C.C., Demetriades, A., Locutura, J., Ottesen, R.T. (Editors), 2011. Mapping the chemical environment of urban areas. Wiley-Blackwell, John Wiley & Sons Ltd., Chichester, U.K., pp. 616.
Kabata-Pendias, A., 2011. Trace elements in soils and plants. 4rd ed, CRC Press. Boca Raton., 534 p.
Kelm, U., Helle, S., Matthies, R., Morales, A., 2009. Distribution of trace elements in soils surrounding the El Teniente porphyry copper deposit, Chile: the influence of smelter emissions and a tailings deposit. Environmental Geology 57, 365-376.
Khaghani, J., Forghani Tehrani, G., 2024. Assessment of the concentration and health risk of potentially toxic elements in agricultural soils of the Bastam Plain (Semnan Province. Kharazmi Journal of Earth Science 10 (1), 234-264.
Kravchenko, J., Darrah, Th.H., Miller, R.K., Lyerly, H.K., Vengosh, A., 2014. A review of the health impacts of barium from natural and anthropogenic exposure. Environmental Geochemistry and Health 36, 797-814.
IARC (International Agency for Research on Cancer), 2016. https://monographs.iarc.who.int/agents-classified-by-the-iarc/.
Li, Z., Feng, X., Li, G., Bi, X., Sun, G., Zhu, J., Qin, H., Wang, J., 2011. Mercury and other metal and metalloid soil contamination near a Pb/Zn smelter in east Hunan province, China. Applied Geochemistry 26 (2), 160-166.
Loska, K., Cebula, J., Pelczar, J., Wiechuła, D., Kwapuliński. J., 1997. Use of enrichment, and contamination factors together with geoaccumulation indexes to evaluate the content of Cd, Cu, and Ni in the Rybnik water reservoir in Poland. Water, Air, and Soil Pollution 93 (1-4), 347-365.
Mazurek, R., Kowalska, J.B., Gąsiorek, M., Zadrożny, P., Wieczorek, J., 2019. Pollution indices as comprehensive tools for evaluation of the accumulation and provenance of potentially toxic elements in soils in Ojców National Park. Journal of Geochemical Exploration 201, 13-30.
Müller, G., 1969. Index of geoaccomulation in sediments of the Phine River. GeoJournal 2, 109-118.
Ou, S., Sun, J., Hu, F., Chen, C., Bi, X., Wu, L., Li, Z., Wang, J., Xiao, T., Cui, J., 2025. Source-oriented and bioaccessibility-based health risk of persistent toxic elements in peri-urban vegetable farm soils of a magacity. Environmental Chemistry and Ecotoxicology 7, 2005-2016.
Parton, W.J., Schimel, D.S., Cole, C.V., Ojima, D.S., 1987. Analysis of factors controlling soil organic matter levels in Great Plains Grasslands 1. Soil Science Society of America Journal 51, 1173-1179.
Rocco, C., Duro, I., Di, R.S., Fagnano, M., Fiorentino, N., Vetromile, A., Adamo, P., 2016. Composite vs. discrete soil sampling in assessing soil pollution of agricultural sites affected by solid waste disposal. Journal of Geochemical Exploration 170, 30-38.
Sawut, R., Kasim, N., Maihemuti, B., Hu, L., Abliz, A., Abdujappar, A., Kurban, M., 2018. Pollution characteristics and health risk assessment of heavy metals in the vegetable bases of northwest China. Science of the Total Environment 642, 864-878.
Shakeri, Z., Forghani Tehrani, G., 2023. Environmental geochemistry, source, and health risk of the potentially toxic elements in the urban soils of Shahrood, Semnan Province. Kharazmi Journal of Earth Sciences 9 (2), 1-25.
Six, J., Conant, R.T., Paul, E.A., Paustian, K., 2002. Stabilization mechanisms of soil organic matter: implications for C-saturation of soils. Plant and soil 241, 155-176.
Soltani-Gerdefaramarzi, S., Ghasemi, M., Gheysouri, M., 2021. Pollution, human health risk assessment and spatial distribution of toxic metals in urban soil of Yazd City, Iran. Environmental Geochemistry and Health 43 (9), 3469-3484.
Shomali, A.R., Khodaverdilo, H., 2012. Contamination of soils and plants along Urmia-Salmas highway (Iran) to some heavy metals. Journal of Water and Soil Science 22, 157-172.
Tomlinson, D.L., Wilson, J.G., Harris, C.R., Jeffrey, D.W., 1980. Problems in the assessments of heavy metal levels in estuaries and formation of a pollution index. Helgolander Meeresuntersuchungen 33, 566–575.
Turekian, K.K., Wedepohl, K.H., 1961. Distribution of the elements in some major units of the earth's crust. Geological Society of America Bulletin 72 (2), 175-192.
USDA, 1999. Soil taxonomy. A basic system of soil classification for making and interpreting soil surveys, Handbook No. 436. Soil Survey Staff, Washington, DC.
USEPA, 1998. Test methods for evaluating solid waste, Method 9045D. EPA, Washington, D.C.
USEPA, 1989. Risk Assessment Guidance for Superfund, Vol. I: Human Health Evaluation Manual. USEPA, Washington DC.
USEPA, 1998. Test Methods for Evaluating Solid Waste, Method 9081A. EPA, Washington, D.
Uugwanga, M.N., Kgabi, N.A., 2020. Assessment of metals pollution in sediments and tailings of Klein Auband Oamites mine sites, Namibia. Environmental Advances 2, 100006.
Xu, H., Hu, P., Wang, H., Croot, P., Li, Zh., Li, Ch., Xie, Sh., Zhou, H., Zhang, Ch., 2025. Identification of the pollution sources and hidden clustering patterns for potentially toxic elements in typical peri-urban agricultural soils in southern China. Environmental Pollution 370, 125904.
Yaftian, Z., Shakeri, A., Hadipourdeshal, M., Rastegari Mehr, M., 2023. Investigating the contamination of heavy mentals in soils of the Sangan mining area, Khorasan-Razavi Province. Kharazmi Journal of Earth Sciences 9 (2), 26-46.
Yakamercan, E., Ari, A., Aygün, A., 2021. Land application of municipal sewage sludge: human health risk assessment of heavy metals. Journal of Cleaner Production 319, 128568.
Yang, Z.P., Lu, W.Z., Long, Y.Q., Bao, X.H., Yang, Q.C., 2011. Assessment of heavy metals contamination in urban topsoil from Changchun City, China. Journal of Geochemical Exploration 108, 27-38.
Yuan, M.Z., Yu, R.L., Hong, Q.H., Ji, Z.H., 2008. Mercury in soils of three agricultural experimental stations with long-term fertilization in China. Chemosphere 72, 1274-1278.
Young, M.H., Green, R.L., Conkle, J.L., McCullough, M., Devitt, D.A. Wright, L., Vanderford, B.J., 2014. Field-scale monitoring of pharmaceutical compounds applied to active golf courses by recycled water. Journal of Environmental Quality 43 (2), 658–670.
Yu, Y., Zhao, C., Zheng, N., Jia, H., Yao, H., 2019. Interactive effects of soil texture and salinity on nitrous oxide emissions following crop residue amendment. Geoderma 337, 1146-1154.
Zhang, M., Cui, L., Sheng, L., Wang, Y., 2009. Distribution and enrichment of heavy metals among sediments, water body and plants in Hengshuihu Wetland of Northern China. Ecological Engineering 35, 563–569.